By default, NDR (5.4.4) of an email sent to a user with non-existent domain is sent to postmaster's mailbox. If you want your users to get NDR when they send email to a wrong email address (domain in this case), you need to remove 5.4.4 code from Transport Configuration.
In Exchange 2010:
In Exchange 2010:
- go to Organization > Hub transport > Global settings > Transport settings
- remove code 5.4.4 from the list
In Exchange 2013/16
- Get-transportConfig to check settings
- Find GenerateCopyOfDSNFor and the codes (if 5.4.4 is on the list)
- Example: {5.4.8, 5.4.4, 5.4.6, 5.2.4, 5.2.0, 5.1.4}
- Copy ALL codes (from bracket to bracket)
- Paste into Notepad
- Remove 5.4.4 from the list (remove 5.4.4, )
- Set-transportConfig -GenerateCopyOfDSNFor "5.4.8, 5.4.6, 5.2.4, 5.2.0, 5.1.4"
Users will get NDR immediately.
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